GeoSciences Soil & Sediment

Characterization & Remediation

“REAL-TIME” SOIL CHARACTERIZATION AND REMEDIATION DEMONSTRATION PROJECT

Argonne National Laboratory, UK, industry and PGDP scientists developed and demonstrated a tailored, site-specific approach to utilize state-of-the-art field instrumentation to conduct a PGDP soil/sediment project from characterization through remediation and verification of cleanup.  The ‘Real Time’ Demonstration Project (RTD) accomplished characterization and cleanup of PCB, metal, and radionuclide contamination on the 16-acre AOC-492 site (Figure 1) in a 3-week field mobilization versus the typical 3-4 years necessary for completing existing iterative field project life cycles.

The Project integrated key conceptual approaches from Argonne National Laboratory, the Adaptive Sampling and Analysis Plan (ASAP) approach, and the Environmental Protection Agency TRIAD approach.   Following Project completion TRIAD and ASAP training was provided to PGDP DOE staff, PGDP Contractor Staff, University staff, EPA Staff, Kentucky regulators and the public.

Preliminary RTD project efforts included rigorous testing to verify performance and project suitability for X-ray Fluorescence (XRF) metal quantification field instruments and PCB field test kits.  XRF performance verification was conducted with the assistance of private industry and PCB field test kit performance verification was conducted cooperatively with USEPA’s Technology Innovation Field Services Division (Las Vegas).

The RTD Project technology suite (Figure 2) included: 1) Logged gamma walkover surveys (GWS) for gamma-emitting radionuclides; 2) Discrete in- situ gamma measurements (Figures 3-6); 3) In-situ High Purity Germanium (HPGe) gamma spectroscopy for radionuclides; 4) In-situ and ex-situ (XRF) for metals including total uranium;  and  5) field test kits for polychlorinated biphenyls (PCBs). Multi-increment sampling and adaptive compositing techniques were included in the dynamic work strategy applied to the study area.  In addition to in-situ and ex-situ measurements accomplished in the field, composite samples were analyzed by fixed laboratory to support the real-time technologies.

The Real Time Technology Application Demonstration Project Final Report and Project Concept Presentations discuss the Project approach and the  application of field and laboratory methods.

RTD Figure 1. AOC-492 Study Area
RTD Figure 2. Workflow for Initial Field Surveys and Sampling
RTD Figure 3. AOC-492 Study Area Gamma Walkover Survey
RTD Figure 4. AOC-492 Study Area Gamma Walkover Survey With Sampling Locations
RTD Figure 5. AOC-492 Study Area ‘Hot Spot’ Pre-Excavation Sample Locations
RTD Figure 6. AOC-492 Study Area FIDLER Survey after Hot Spot Removal
Gamma Walkover Survey Using FIDLER (detector) and LARADS geolocation instrument
XRF metals detection in-situ, on composited sample and in mobile field lab
HPGe (high purity germanium detector) for field identification of radioisotopes

Project Team

Dr. Robert Johnson, Applied Environmental Science, Argonne National Library (Co-PI)
Dr. John Volpe, Kentucky Research Consortium for Energy and Environment, Kentucky Water Resources Research Institute, University of Kentucky (Co-PI)
Dr. Richard Bonczek, Technical Project Manager & Risk Assessor, Portsmouth-Paducah Project Office, U.S. Department of Energy
Jon Richards, Health Physicist, USEPA Region IV
Steve Meiners, Radiation Safety and Industrial Health and Safety, Tricord, Inc.
Deana Crumbling, Technology Innovation and Field Services Division, U.S. Environmental Protection Agency
Mike Dillon, Eberline Services
Dave Lawrence, Eberline Services
Dave Lasher, Eberline Services
Larry Payne, Tricord, Inc.
Jason Boulton, Geo Consultants
Windy Gregory, Tricor, Inc.
Hipolito Hernandez, Eberline Services
Chris Higgins, Eberline Services
Jim Craig, Eberline Services
Frazer Johnstone, Paducah Remediation Services
James Kipp, Associate Director, Kentucky Water Resources Research Institute (KWRRI), University of Kentucky
Stephanie Jenkins, KRCEE
Steve Hampson, Associate Director, Kentucky Research Consortium for Energy and Environment (KRCEE), Center for Applied Energy Research, University of Kentucky

Project Documents

Project Concept Presentation Johnson, R.L., Case Study: ASAP Techniques in Support of Precision Excavation
Project Concept Presentation Johnson, R.L., PGDP Case Study Improving Volume w Dynamic Work Strategies
Project Concept Presentation Johnson, R.L., Strategies and Tools for Improved Management of Uncertainties at Contaminated Sites
Project Concept Presentation Johnson, R.L., An Introduction to the Triad Approach
Project Final Report Volpe, J.A., Johnson, R.L. & Hampson, S., Real Time Technology Application Demonstration Project Final Report, KRCEE Doc# P18.32, 2008
Project Supporting Study Document Crumbling, D., USEPA TIFSD Soil PCB Pilot Study Experimental Design Plan, 2008
Project Supporting Study Report Johnson, R.L., Real Time Demonstration Project XRF Performance Evaluation Report for Paducah Gaseous Diffusion Plant AOC 492 , April 2008.
USEPA Newsletter Bonczek, R., Johnson, R.L., Hampson, S., ‘Single Field Mobilization Completes Site Investigation and Removal Actions’, in USEPA Technology News and Trends, Issue 40, January 2009, pp. 3-4.
USEPA Quick Reference Fact Sheet Bonczek, R., Johnson, R.L., Hampson, S., “Profile: Paducah Gaseous Diffusion Plant, Paducah, KY,” in Green Remediation: Best Management Practices for Excavation and Surface Restoration. United States Environmental Protection Agency Office of Solid Waste and Emergency Response, EPA 542-F-08-012, December 2008.
Project Supporting Document Argonne National Laboratory, Field Sampling Plan for AOC 492, Real Time Measurement Demonstration Project, KRCEE 18.11 2008d, December 2007.
Supporting Professional Presentation Richards, J. (USEPA Region IV), Real-Time Demonstration Project: Dynamic, Real-Time Characterization, Remediation, and Verification of Cleanup for PCBs and Radionuclides in Soil/Sediment at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky,  USEPA Radiation Superfund Meeting, April 2008. (not linked)
Supporting Professional Presentation Volpe, J.A., Real-Time Demonstration Project: Dynamic, Real-Time Characterization, Remediation, and Verification of Cleanup for PCBs and Radionuclides in Soil/Sediment at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky,  Conference of Radiation Control Program Directors Annual Meeting, Columbus, Ohio, February 2009. (not linked)
Supporting Professional Presentation Johnson, R.A., Real-Time Demonstration Project: Dynamic, Real-Time Characterization, Remediation, and Verification of Cleanup for PCBs and Radionuclides in Soil/Sediment at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky, Interstate Technology and Regulatory Council (ITRC) National Meeting: Presentation and Discussion, Louisville, Kentucky, December 2009. (not linked)
Supporting Presentation Hampson, S., Real Time Remedial Demonstration Project Introduction, PGDP Citizens Advisory Board (CAB) Presentation, Paducah, Kentucky, May 2006. 
Supporting Presentation Hampson, S., Real Time Demonstration Project Introduction, PGDP Site Managers Meeting Presentation, Kevil, Kentucky, May 2006. (above)
Supporting Presentation Hampson, S., Real Time Demonstration Project Introduction, KRCEE Quarterly Meeting Presentation, Lexington, Kentucky, May 2006. (above)

DESIGN OF COST-EFFECTIVE, REAL-TIME IMPLEMENTABLE,
SEDIMENT AND CONTAMINANT RELEASE CONTROLS

UK Biosystems and Agricultural Engineering Department and KWRRI developed alternative, readily implementable, design options for integrated storm water and sediment control systems for PGDP Outfalls 008, 011 and 015.

The project’s remedial options design process utilized the SEDCAD surface water and sediment release model with historical PGDP watershed flow and sediment concentrations.  Outfall watershed discharge and sediment loading were modeled.

Remedial options were required to meet performance objectives, be cost effective, readily implementable, and require minimal excavation disturbance for placement.

Project remedial options and recommendations for future watershed monitoring are provided in the project final report.

Project Team

Dr. Richard Warner, Associate Professor, Biosystems and Agricultural Engineering, University of Kentucky (PI)
Dr. Lindell Ormsbee, PE, UK-Civil Engineering, Director Ky. Water Resources Research Institute, Director Superfund Basic Research Program Translation Core, Director Ky. Research Consortium for Energy & Environment (Co-PI)
Dr. John Volpe, Kentucky Research Consortium for Energy and Environment, Kentucky Water Resources Research Institute, University of Kentucky
Steve Hampson, Associate Director, Kentucky Research Consortium for Energy and Environment (KRCEE), Center for Applied Energy Research, University of Kentucky

SURFACE WATER TOTAL MAXIMUM DAILY LOAD (TMDL) DEVELOPMENT

The Kentucky Water Resources Research Institute (KWRRI), Murray State University, and UK Civil Engineering conducted an extensive hydrologic and water quality evaluation of the PGDP and associated watersheds.

TMDL Development Project Phase 1 compiled and assessed available surface water flow and water quality data to develop TMDL criteria for surface water associated with the PGDP.

Based on TMDL Phase 1 data assessment it was determined that additional field data were needed to complete evaluation and recommendations for Cu, Fe, Pb, and Hg in Bayou and Little Bayou Creeks. During 2009 the TMDL Phase 2 Project collected supplemental metal-of-interest data from Bayou Creek, Little Bayou Creek, and reference locations.

The project final report discusses the evaluation of supplemental data and provides TMDL recommendations.

Field data locations for the collection of metals data for Phase II of the TMDL project.

Project Team

Dr. Lindell Ormsbee, PE, UK-Civil Engineering, Director Ky. Water Resources Research Institute, Director Superfund Basic Research Program Translation Core, Director Ky. Research Consortium for Energy & Environment (Co-PI)
Dr. Chandramouli Viswanathan, Adjunct Faculty, Kentucky Water Resources Research Institute/College of Engineering, University of Kentucky
Andy Kellie, Professor (emeritus), Industrial and Engineering Technology, Murray State University
Dr. Michael Kemp, Professor, Industrial Engineering & Technology, Murray State University
Jane Benson, Mid-America Remote Sensing Center, Hancock Biological Station, Murray State University
Michael Matthews, Industrial Engineering and Technology, Murray State University
Matthew Phillip, Industrial Engineering and Technology, Murray State University
Ben Albritton, Scientist, Kentucky Water Resources Research Institute (KWRRI), University of Kentucky
Clay Johnson, Research Assistant, Kentucky Water Resources Research Institute (KWRRI), University of Kentucky
Steve Meiners, Radiation Safety and Industrial Health and Safety, Tricord, Inc.

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